In the catalyst systems bearing mono ( imino) pyridine ligand, it seems that the substitute attached to the ortho position of phenyl ring has a beneficial influence on the activity while substitute group in the para position has a negative effect. 此外,在含有单亚胺吡啶配体的催化剂体系中,亚胺基苯环上邻位取代基对于催化活性有利,对位取代基则会抑制催化剂活性。
The base peak at m/ z 191 is formed with the loss of a neutral molecule via the ortho effect; 基峰m/z191是由M~+通过邻位效应失去HN(CH3)2中性分子形成的;
We also found that the ortho ester functional groups have an accelerating effect for the reaction to proceed and the steric hindrance effect of ester is not apparent. 研究还发现邻位酯基对反应的进行有明显的促进作用,而酯基的空间位阻效应对反应影响不明显。